![]() An aldehyde is produced as an intermediate during this reaction, but it cannot be isolated because it is more reactive. Note that NaBH 4 is not strong enough to convert carboxylic acids or esters to alcohols. Carboxylic acids can be converted to 1 o alcohols using Lithium aluminium hydride (LiAlH 4 ). New Light on Alkaloid Biosynthesis and Future Prospects. Reduction of carboxylic acids and esters. "Increasing the Pace of New Discoveries in Tropane Alkaloid Biosynthesis". ↑ Jirschitzka, Jan Dolke, Franziska d’Auria, John C.Journal of the American Chemical Society. "A revision of the generally accepted hypothesis for the biosynthesis of the tropane moiety of cocaine". 2-Carbomethoxy-3-tropinone: An advanced intermediate in the biosynthesis of cocaine". "The Three-dimensional Structure of the Cocaines. "Two-carbon bridge substituted cocaines: Enantioselective synthesis, attribution of the absolute configuration and biological activity of novel 6- and 7-methoxylated cocaines". ↑ Simoni, Daniele Roberti, Marinella Andrisano, Vincenza Manferdini, Monica Rondanin, Riccardo Invidiata, Francesco Paolo (1999). ![]()
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